Msds information for oil spill dispersants corexit 9500. Analysis of eight oil spill dispersants using in vitro tests for endocrine and other biological activity. Aug 01, 2010 the massive oil spill from the deepwater horizon oil platform in the gulf of mexico has led to the use of correspondingly large volumes of the oil spill dispersant corexit 9500 nalco energy services, l. Let me get you started with this table on toxicity of the dispersants listed on the. On heavy oils use zi400 directly on the spill, or up to approximately a. Let me get you started with this table on toxicity of the dispersants listed on the ncp product schedule. National contingency plan product schedule toxicity and effectiveness summaries. Dispersant science alaska department of environmental conservation division of spill prevention and response dr. Msds information for oil spill dispersants corexit 9500 and.
Guidelines for the use of dispersants for combating oil pollution at sea in the mediterranean region part ii. Because of this large scale use there is a critical need. Comparative acute toxicity of eight oil spill dispersants, louisiana crude oil and chemically dispersed oil to two gulf of mexico aquatic species. Steffek interspill 2015 dispersant comparison slides. The eight oil spill dispersants analyzed are listed in table s1. Application of oil dispersants in addition to mechanical recovery techniques skimming and booming and in situ burning, oil dispersants were used to prevent landfall of the oil in the deepwater horizon spill beginning in early may responders began injecting dispersants at the source of the release 1500m.
Dispersants do not remove oil from the water, but instead breakthe oil slick into small droplets. Zi 400 pdf 11k approximately 75,000 gallons of corexit 9500 is currently stockpiled in alaska for potential use. Comparative testing of corexit ec9500a, finasol osr52, accell clean dwd, and zi 400 at ohmsett in a simulated arctic environment timothy steffek bureau of safety and environmental enforcement timothy. What tests were conducted in phase ii of dispersant toxicity testing. Oil spill dispersant may be used for the beach and shore cleaning. Comparative toxicity of chemical oil dispersants sea grant in the. Gulf spill oil dispersants associated with health symptoms. Oil spill dispersant,rxsol oil spill dispersant,water emulsifier, ecofirendly marine chemical. The oil spill dispersant, corexit 9500, used in the bp deepwater horizon oil spill, was analyzed by highperformance liquid chromatographyion trap mass spectrometry with electrospray ionization. The oil spill science and technology work group joint industrygovernment work group of api. Jun 15, 2010 msds for corexit 9500a pdf msds corexit 9527a pdf according to the deepwater horizon response unified commands website, as of june 14, 2010, over 1,262,000 gallons of dispersants have been used as part of bps oil spill cleanup efforts. An oil dispersant is a mixture of emulsifiers and solvents that helps break oil into small droplets following an oil spill.
We observed statistically significant er activity for two of the dispersants, nokomis 3f4 and zi 400, in the attagene transer. This product is not recommended for any industrial, professional or consumer use other than the. Samples were shipped directly from the manufacturers to the epa for. Analysis of eight oil spill dispersants using rapid, in. Usepa dispersant toxicity testing june 30, 2010 1 comparative toxicity of eight oil dispersant products on two gulf of. Oil alone had similar toxicity to mysid shrimp as the dispersantoil mixtures, with exception of the mixture of nokomis 3aa and oil, which was found to be more toxic. In general, dispersion efficiency increased with increase in salinity for most oildispersant combinations. Scope this specification relates to oil spill dispersants for application at sea or on beaches and to the procedures adopted in the uk before any dispersant can be so used.
The tests were conducted using an established contract testing. Msds for corexit 9500a pdf msds corexit 9527a pdf according to the deepwater horizon response unified commands website, as of june 14, 2010, over 1,262,000 gallons of. Oil dispersantcleaner biodegradable organic degreaser. Large amounts of dispersants have been used on the oil from the deepwater horizon spill and concern has arisen about the toxicity of the dispersants. Finasol is osr 52 is no longer expected to be delivered to alaska. Although significant steps have been taken over the last 15 years to reduce the size and frequency of oil spills, the sheer volume of petroleum consumed in this country and the complex production and. Procedures a qualification a dispersant which has been found to conform to the requirements of the. Because of this large scale use there is a critical need to understand the potential for toxicity of the currently used dispersant and potential alternatives, especially given the limited toxicity testing information that is available. Effects of oil and chemically dispersed oil in the environment. Nov 24, 2012 oil spill dispersant,rxsol oil spill dispersant,water emulsifier, ecofirendly marine chemical.
The deepwater horizon oil spill has led to the use of 1 m gallons of oil spill dispersants, which are mixtures of surfactants and solvents. August 2, 2010 dispersants toxicity testing phase ii questions and answers q1. Gulf spill oil dispersants associated with health symptoms in cleanup workers. Analysis of eight oil spill dispersants using rapid, in vitro tests for. If an oil spill occurs in san juan county marine waters, responders may use. Appendix a indicates that zi400 does in fact contain an npe. Adecs dispersant fact sheet pdf 324k introduction to dispersants. Environmental protection agency ncp product schedule. This research work has successfully created a set of empirical data on three oils and. Comparative toxicity of eight oil dispersant products on two.
Epaord appendices for dispersant in vitro tests june 29, 2010 s2 appendix a oil spill dispersants and reference chemicals appendix a. This research work has successfully created a set of empirical data on three oils and two dispersants that could serve as an input to the oilspill simulation models being developed by epa. Orange release is a water soluble, highly rinsable combination of blended citrus oils, mild natural detergents, and biodegradable surfactants that work extremely well in fresh or brine water. National contingency plan product schedule toxicity and. Comparative testing of corexit ec9500a, finasol osr52. Nearly two million gallons of dispersants were used at the waters surface and a mile below the surface to combat oil during the. Analysis of eight oil spill dispersants using in vitro. Basic information on dispersants and their application page 1 p a r t ii basic information on dispersants and their application 1. Comparative testing of corexit ec9500a, finasol osr 52. Steffek, timothy, bittler, kimberly, and guarino, alan 2017 large scale comparative testing of corexit ec9500a, finasol osr 52, accell clean dwd, marine dblue clean, and zi 400 at ohmsett. He also has experience conducting oil spill research in cold environments and was one of the founders of the arctic and marine oil spill program amop. These educational fact sheets are an introduction to dispersant use and effect.
Corexit ec9500a, finasol osr 52, accell clean dwd, marine dblue clean and zi 400. Solidus industries world class cleaning products for. Epa national contingency plan product schedule february. Epa national contingency plan product schedule february, 2010. Overall, we find zi 400 to be highly effective, without being too harsh so as to damage the surface finish of painted, powder coated and gelcoat items as is the case with many other cleaning products.
The chemical sprayed on the 2010 bp oil spill may not have helped crucial petroleummunching microbes get rid of the slick, a new study suggests. Nov 09, 2015 the chemical sprayed on the 2010 bp oil spill may not have helped crucial petroleummunching microbes get rid of the slick, a new study suggests. Analysis of seven oil spill dispersants using in vitro. Z1 400 s green credentials enable us to have minimal impact on the environment, which fits in with our environmental policy. Toxicity testing of dispersants epa response to bp spill. Small droplets are easier to disperse throughout a water volume, and small droplets may be more readily biodegraded by microbes in the water. Small droplets are easier to disperse throughout a water volume, and small droplets may be. These toxicity tests were conducted as part of an overall assessment of bps use of corexit 9500 in response to the oil spill in the gulf. Graham, christine hale, emily maungdouglass, stephen sempier, ladon swann, and monica wilson. Orange release is a water soluble, highly rinsable combination of blended citrus oils, mild natural detergents, and. Large scale comparative testing of corexit ec9500a, finasol. The study was conducted to better understand and compare the effectiveness of various dispersants under large scale test conditions. Accell clean dwd, and zi 400 at ohmsett in a simulated. Analysis of eight oil spill dispersants using rapid, in vitro tests for endocrine and other biological activity.
May 25, 2012 first, the dispersant is applied to the water surface. Given this fact, questions have arisen about the toxicity of the chemicals used as dispersants themselves. Dwd, and zi 400 at ohmsett in a simulated arctic environment timothy steffek bureau of safety and environmental enforcement. Epaord dispersant in vitro testing june 30, 2010 4 introduction background the deepwater horizon oil spill has led to the use of large amounts of dispersant as part of the integrated approach dealing with the oil spill. Updates to manufacturer contact information for 400zi, aka zi 400 oil spill dispersant d new listings to the product schedule. Similarly, the lempertkeeneseastrand oil spill prevention and response ospr act of 1991 established the oil spill response program in california and directed the administrator of ospr to develop a research program designed to examine the effects of oil and oil spill response technologies on the environment. Interspill ohmsett the national oil spill response. Oil dispersant cleaner biodegradable organic degreaser. August 2, 2010 dispersants toxicity testing phase ii.
Analysis of eight oil spill dispersants using in vitro tests. Zi400 may be applied by the usual method of aerial or boat spraying. Wave action and turbulence then disperse the oil dispersant mixture into the water column, so that the oil that had been concentrated at the surface is diluted within the water column. Five dispersants were selected from the epas ncp product schedule and tested on a gulf of mexico crude oil. Only go outside for food, health reasons or work but only if you cannot work from home if you go out, stay 2 metres 6ft away from other people at all times.
Analysis of eight oil spill dispersants using rapid, in vitro. Scope this specification relates to oil spill dispersants for application at sea or on beaches and to the procedures adopted in the uk before any dispersant. Interchem, interchem limited, zi400 oil spill dispersant. Toxicity testing of dispersants epa response to bp spill in. Next, molecules of the dispersant attach to the oil, causing it to break into droplets. Comparative toxicity of eight oil dispersant products on two gulf of mexico aquatic test species. First, the dispersant is applied to the water surface. Updated at noon with comment from bps steve rinehart. Comparative testing of corexit ec9500a, finasol osr52, accell clean dwd, and zi 400 at ohmsett in a simulated arctic environment timothy steffek bureau of safety and environmental enforcement.
Field tests and spill studies on dispersant use have generally found that the use of dispersants has some. Dispersant effectiveness on oil spills impact of salinity. Oil spill dispersants are complex mixtures of two basic components 1. Overview of oil spill dispersant efficacy and effects. However, the ability of the product to disperse the actual spilled oil also. Pdf advice on the use of chemical dispersants for oil spills in.
Comparative toxicity of eight oil dispersant products on. Comparative testing of corexit ec9500a, finasol osr 52, accell clean dwd, and zi 400 at ohmsett in a simulated arctic environment june 2, 2016 1 page executive summary over 30 years of dispersant effectiveness research has been conducted in laboratory, wave basin, and field studies, including under arcticlike conditions. Pdf oil dispersant effectiveness and ecological consequences in. Before using oil spill dispersant on beaches, the local environmental, social, economic and political consideration should be taken into. Once oil has penetrated saltmarshes, reed beds and tidal flats. Dispersant is a term used to label oil spill treating chemicals that promote the. The environmental protection agency informed bp officials late. Where application is justified, the most appropriate method of use will depend on the type of shore line, type of oil and amount. This product is not recommended for any industrial, professional or consumer use other than the intended uses above and the instructions written in this safety data sheet. Dispersant is a term used to label oil spill treating chemicals that promote the breakdown of a surface slick into small droplets of oil, which more. Environmental protection agencys epa office of emergency management oem regulations implementation division rid compiled the national oil and hazardous. Large scale comparative testing of corexit ec9500a.